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Generously butter the inside of 4 ramekins, or small pudding tins.
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Whisk together the egg yolks, eggs, and sugar in a bowl until light and fluffy.
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Melt the chocolate and the butter in the microwave (on a low setting and check continuously).
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Stir the butter/chocolate into the egg/sugar mixture until combined.
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Add the liqueur to the mixture and stir again.
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Finally, add the cocoa powder and the flour to the bowl and stir.
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Carefully divide the batter between the prepared tins. Tap on the worksurface to remove any bubbles in the mixture.
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Place the tins into the fridge for 30 minutes.
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Meantime, preheat the oven to 220C/Gas Mark 7.
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When ready, put the tins into an oven dish, and pour in boiling water to create a bain Marie.
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Bake in the oven for 10-12 minutes.
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When gently baked on the top (it should be 'just' baked and still soft on the inside), remove from the oven and very carefully use a palate knife to ensure it doesn't stick to the sides of the tin.
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Turn out onto a plate - this works best while still hot, but please be careful!
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Serve with a large spoon of vanilla ice cream.